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1. Yang, Y. Y.; Xiao, Y.; Li, B.; Chen, Y. G.; Guo, P. H.; Zhang, B. B.; Zhang, X. M.*, Stereochemically Active Lone-Pair Containing Metal Substitution in Polar Axis toward a Giant Phase-Matchable Optical Nonlinear Silicate Crystal Li3(OH)PbSiO4. J. Am. Chem. Soc. 2023, 145(41), 22577–22583.

2. Yang, Y.; Qian, Y.; Luo, Z.; Li, H.; Chen, L.; Cao, X.; Wei, S.; Zhou, B.; Zhang, Z.; Chen, S.; Yan, W.; Dong, J.; Song, L.; Zhang, W.; Feng, R.; Zhou, J.; Du, K.; Li, X.; Zhang, X.-M.; Fan, X. Water induced ultrathin Mo2C nanosheets with high-density grain boundaries for enhanced hydrogen evolution. Nature communications 2022, 13, 7225.

3. Zhang, L. J.; Ma, L. J.; Yuan, J. C.; Tang, Z. Y.; Zhang, X. M.*, Tuning Band Structures of Hf-PCN-224(M) for β-Carbonyl C(sp3)-H bond Activation and Difunctionalization: Tandem C(sp3) Radical Cross-coupling through Photoredox. Appl. Catal. B: Environ. 2022, 321, 122049.

4. Fu, D. Y.; Xin, J.; He, Y.; Wu, S.; Zhang, X.;Zhang, X. M.*;Luo, J., Chirality-Dependent Second-Order Nonlinear Optical Effect in 1D Organic-Inorganic Hybrid Perovskite Bulk Single Crystal.Angew Chem. Int. Ed.2021,60(36), 20021-20026.

5. Gao, H.; He, Y. B.; Hou, J. J.;Zhang, X. M.*, In Situ Aliovalent Nickle Substitution and Acidic Modification of Nanowalls Promoted Proton Conductivity in InOF with 1D Helical Channel.ACS Appl. Mater. Interfaces2021,13(32), 38289-38295.

6. Zhao, Y. W.; Guo, L. E.; Zhang, F. Q.; Yao, J.;Zhang, X. M.*, Turn-On Fluorescence Enantioselective Sensing of Hydroxyl Carboxylic Enantiomers by Metal-Organic Framework Nanosheets with a Homochiral Tetracarboxylate of Cyclohexane Diamide.ACS Appl. Mater. Interfaces2021,13(17), 20821-20829.

7. Yang, Y.; Qian, Y.; Li, H.; Zhang, Z.; Mu, Y.; Do, D.; Zhou, B.; Dong, J.; Yan, W.; Qin, Y.; Fang, L.; Feng, R.; Zhou, J.; Zhang, P.; Dong, J.; Yu, G.; Liu, Y.;Zhang, X.M.*; Fan, X. O-coordinated W-Mo dual-atom catalyst for pH-universal electrocatalytic hydrogen evolution.Science Advances2020,6, eaba6586.

8. Qu, M.; Zhang, F. Q.; Wang, D. H.; Li, H.; Hou, J. J.;Zhang, X. M.*Observation of Non-FCC Copper in Alkynyl-Protected Cu53 Nanoclusters.Angewandte Chemie2020,59, 6507-6512.

9. Jia, Y. J.; Chen, Y. G.; Guo, Y.; Guan, X. F.; Li, C.; Li, B.; Liu, M. M.; Zhang, X. M.* LiM(II) (IO3 )3 (M(II) =Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of alpha-LiIO3. Angewandte Chemie 2019, 58, 17194-17198.

10. Fan, X.; Liu, Y.; Chen, S.; Shi, J.; Wang, J.; Fan, A.; Zan, W.; Li, S.; Goddard, W. A.; Zhang, X.-M.* Defect-enriched iron fluoride-oxide nanoporous thin films bifunctional catalyst for water splitting. Nature Commun 2018, 9, 1809.

11. Qu, M.; Li, H.; Xie, L.-H.; Yan, S.-T.; Li, J.-R.; Wang, J.-H.; Wei, C.-Y.; Wu, Y.-W.; Zhang, X.-M.* Bidentate Phosphine-Assisted Synthesis of an All-Alkynyl-Protected Ag74 Nanocluster. J. Am. Chem. Soc. 2017, 139, 12346-12349.

12. Wang, J. H.; Zhang, Y.; Li, M.; Yan, S.; Li, D.; Zhang, X. M.* Solvent-Assisted Metal Metathesis: A Highly Efficient and Versatile Route towards Synthetically Demanding Chromium Metal-Organic Frameworks. Angew. Chem. Int. Ed. 2017, 56, 6478-6482.

13. Zhang, X.-M.*; Sarma, D.; Wu, Y.-Q.; Wang, L.; Ning, Z.-X.; Zhang, F.-Q.; Kanatzidis, M. G. Open-Framework Oxysulfide Based on the Supertetrahedral [In4Sn16O10S34]12– Cluster and Efficient Sequestration of Heavy Metals.J. Am. Chem. Soc.2016,138, 5543-5546.

14. Zhang, X.-M.*; Lv, J.; Ji, F.; Wu, H.-S.; Jiao, H.; Schleyer, P. v. R. A Perfectly Square-Planar Tetracoordinated Oxygen in a Tetracopper Cluster-Based Coordination Polymer.J. Am. Chem. Soc.2011,133, 4788-4790.

15. Zhang, X. M.*; Zhao, Y. F.; Zhang, X. W.; Chen, X. M. A Tetrazolate- and Cyano-Bridged Homometallic Mixed-Valence Copper(I,II) Molecular Ferrimagnet.Adv. Mater.2007,19, 2843-2846.

16. Zhang, X.-M.*; Hao, Z.-M.; Zhang, W.-X.; Chen, X.-M. Dehydration-Induced Conversion from a Single-Chain Magnet into a Metamagnet in a Homometallic Nanoporous Metal–Organic Framework.Angew. Chem. Int. Ed.2007,46, 3456-3459.

17. Zhang, X.-M.*; Fang, R.-Q.; Wu, H.-S. A Twelve-Connected Cu6S4 Cluster-Based Coordination Polymer. J. Am. Chem. Soc. 2005, 127, 7670-7671.

18. Zhang, X.-M.; Tong, M.-L.; Chen, X.-M. Hydroxylation of N-Heterocycle Ligands Observed in Two Unusual Mixed-Valence CuI/CuII Complexes.Angew. Chem. Int. Ed.2002,41, 1029-1031.